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Chinese telecom giant Huawei Technologies became the world's No. 1 applicant for international patents in 2014.
The US has few options to deal with Pyongyang's cyber attack on a major Hollywood studio.
The International Telecommunications Union (ITU) report also underlines the urban-rural digital divide in countries like India.
Deals inked include agreement on delivery of Russian natural gas to China via the western route.
Xi will hold talks with his Venezuelan counterpart Nicholas Maduro on Sunday to boost ties with the Latin American ally.
The Chinese President also discussed advancing the plan for creating an Asia-Pacific free trade area.
On Monday, the Chinese Internet Media Research Center revealed that China has been "a main target" of US secret surveillance.
A US grand jury indicted five Chinese military officers of hacking into American companies to steal trade secrets.
China has signed 16 agreements with Ethiopia during the state visit of Chinese Premier Li Keqiang.
Recent trade disputes have strained ties between China and the EU.